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What you could do is take the duotone and create a clipping path of the forground and save. Reopen the original duo and create a clipping path of the background and convert to a grayscale and save as a tiff. Bring the grayscale tiff into your document, select it and choose the color you want it to be in your swatch pallet. Then bring in your duotone using the same exact x and y coordinance as the colored tif. Make sure the clipping path in the duo is active and you should have a 3 spot color pic with a different colored background.
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