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If you happen to own ProfileMaker (Packaging edition) thay have in their MultiColor profiling module a feature called Generic Output Profile (GoP) that allows you to alter one of the channels to another color and recreate the profile, so theoretically, you could change your Reflex Blue to another color, along with other adjustments, such as color sequence on press, and then regenerate the profile. I'm not yet licensed for MultiColor profiling (other than Hexachrome) with ProfileMaker, so I haven't tried this feature, but it looks interesting, though its hard to say how effective this feature is.
Back to your original issue though, is the press rendering the same or close Lab values for Reflex Blue and process colors as that of your proof? For example, what's the delta E between the Solid Reflex Blue patch of the press versus your proof? Are the gradients close as well?
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